32. For the process X-(g) → X-(aq), select the ion with the most negative value of ΔH.
(A) F-
(B) Cl-
(C) Br-
(D) I-
(E) all positive values

33. Which of the following noble gases has(have) been observed to form compounds? (A) He and Ar (B) Kr and Xe (C) Xe (D) Ar, Kr and Xe (E) The noble gases never form compounds because they have filled outer shells.

34. Which of the following statements is(are) true? (A) the rate of dissolution of a solid in a liquid always increases with increasing temperature (B) the solubility of a solid in a liquid always increases with increasing temperature (C) according to Henry's law, the amount of gas dissolved in a solution is directly proportional to the pressure of the gas above the liquid (D) two of these statements are true (E) all of these statements are true

35. How many different possible tetramethylbenzenes exist? (A) 2 (B) 3 (C) 4 (D) 5 (E) 6

36. Which of the following is optically active (that is, chiral)? (A) dimethylamine (B) difluoromethane (C) 2-chloropropane (D) 2-chlorobutane (E) 1-bromohexane

37. Oxidation of a primary alcohol results in a(n)__ and oxidation of a secondary alcohol results in a(n)__ (A) carboxylic acid, amine (B) aldehyde, ketone (C) ester, ether (D) ketone, aldehyde (E) amine, carboxylic acid

38. What is the complementary nucleic acid sequence for the DNA sequence GAC TAC GTT GGC? (A) GAC TAC GTT GGC (B) TCA GCA TGG CTA (C) CGA GTG CAT CAG (D) CTG ATG CAA CCG (E) GCG AAG GGG TTG

39. When heat is added to proteins, the hydrogen bonding in the secondary structure breaks apart. What are the algebraic signs of ΔH and ΔS for the denaturation process? (A) both ΔH and ΔS are positive (B) both ΔH and ΔS are negative (C) ΔH is positive and ΔS is negative (D) ΔH is negative and ΔS is positive (E) ΔH is positive and ΔS is 0.

40. Which of the following polymers is not based on a substituted ethylene monomer? (A) nylon (B) polyvinylchloride (C) Teflon (D) polystyrene (E) polypropylene

41. In the DNA molecule, thymine is always bonded to (A) adenine (B) cytosine (C) guanine (D) A or B (E) B or C

42. What reason is given for the stability of C-C, N-N, and O-O bonds, compared to the instability of Si-Si, P-P, and S-S bonds? (A) their metallic character varies greatly (B) there are large differences in their ionization energies (C) there are large differences in their electronegativities (D) there are large differences in their abilities to form strong pi bonds (E) none of these

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