109年 - [非官方正解]109 國立高雄大學_碩士班招生考試_應用化學系：普通化學#103029

科目：研究所、轉學考(插大)◆普通化學 | 年份：109年 | 選擇題數：20 | 申論題數：4

試卷資訊

所屬科目：研究所、轉學考(插大)◆普通化學

選擇題 (20)

1. Which of the following molecules is non-polar? (A) NH3 (B) H2O (C) XeF4 (D) ClF3 (E) none of these
2. Use the molecular orbital model to predict the (magnetism, bond order) of the N2 + ? (A) (paramagnetism, 3) (B) (diamagnetism, 3) (C) (diamagnetism, 2) (D) (paramagnetism, 2) (E) none of these
3. A sample containing 0.5 mole of He gas at a temperature of 300 K and a pressure of 0.6 atm torr is heated to 380 K and a pressure of 1.9 atm. Calculate the change in volume that occurs? (A) -12.3 L (B) -9.3 L (C) 9.3 L (D) 5.2 L (E) none of these
4. Which of the following statements is true? (A) If a substance is soluble, it must be an electrolyte. (B) The bonds between hydrogen and oxygen within a water molecule can be characterized as intermolecular forces. (C) The buffered solution will not change its pH very much even if a strong base is added. (D) The total energy of the universe increases, while the entropy increases. (E) none of these
5. Excluding cyclic compounds, how many possible isomers exist for C4H8? (A) 2 (B) 3 (C) 4 (D) 5 (E) none of these
6. Balance the following redox equation using the smallest integers possible and select the correct coefficient for the bromide anion, Br⁻ . 
617b496b45282.jpg (A) 1 (B) 2 (C) 4 (D) 5 (E) none of these
7. Which of the following statements is correct? (A) An excited atom can return to its ground state by absorbing electromagnetic radiation (B) 1s orbital in He+ is larger (probability density is shifted outward) than the 1s orbital in H (C) Energy of electromagnetic radiation increases as its frequency decreases (D) The binding forces in a molecular solid include London dispersion forces (E) none of these

8. The oxidation and coordination numbers of cobalt (Co) in the compound K[Co(C2O4)2(H2O)2] (where 617b49e4b8f4d.jpg = oxalate), respectively: (A) 3 and 6 (B) 3 and 4 (C) -1 and 4 (D) -1 and 6 (E) none of these

9. Select the correct name for the following compound. 617b49a06493f.jpg(A) 2-ethyl-3-pentene (B) 4-ethyl-2-pentene (C) 3-methyl-4-hexene (D) 4-methyl-2-hexene (E) none of these

10. The heat of vaporization for 1.0 mole of water at 373 K and 1.0 atm is 40.55 kJ/mol. Calculate ΔS (J/K mol) for the process 617b4a0c1c049.jpg at 373 K. (A) +109 (B) -109 (C) +406 (D) 0 (E) none of these

11. Consider the following electrode potentials: 617b4a3fea02f.jpg

Which one of the reactions below will proceed spontaneously from left to right? (A) 617b4a6631de7.jpg (B) 3617b4a7053e47.jpg(C) 617b4a79636d2.jpg (D) 617b4a825782d.jpg (E) None of these
12. The gas-phase reaction between methane and diatomic sulfur is given by the equation 
617b4ab2e93bc.jpg
At 550 oC the rate constant for this reaction is 617b4ac7191c7.jpg. What is the order of the reaction? (A) zero (B) first (C) second (D) third (E) More information is needed to determine the overall order.
13. How many milliliters of 6.0 M HNO3 are needed to prepare 300.0 mL of 0.50 M HNO3? (A) 25.0 (B) 20.2 (C) 15.2 (D) 10.5 (E) none of these
14. Iron is produced from its ore by the reactions (unbalanced): 
617b4b4f5b9e5.jpg
How many moles of O2(g) are needed to produce 6.4 moles of 617b4b658dea2.jpg? (A) 2.3 (B) 4.8 (C) 6.4 (D) 1.2 (E) none of these

15. Identify the functional group circled.617b4b781a37f.jpg (A) alcohol (B) ketone (C) aldehyde (D) carboxylic acid (E) none of these

16. A sample is composed of carbon 617b4b8ec57a4.jpg, hydrogen (H), and chlorine (Cl). When a 0.250 g sample was subjected to combustion analysis, 0.451 g of CO2 and 0.0617 g of H2O. What is its empirical formula? (C = 12.01 amu, O = 16.00 amu, Cl = 35.45 amu, H=1.01 amu) (A) C3H2Cl (B) C2H5Cl (C) C2H4Cl2 (D)CH3Cl (E) none of these
17. 37.5 mL of a 0.250 M Na2CO3 solution is added to 46.5 mL of 0.120 M NaCl. What is the concentration (M) of sodium ion (Na⁺ ) in the final solution? (A) 0.15 M (B) 0.29 M (C) 0.58 M (D) 0.89 M (E) none of these.
18. What is the molecular shape of SF4 as predicted by the VSEPR theory? (A) Tetrahedral (B) Square planar (C) T shaped (D) Seesaw (E) none of these

19. 6.45 g of liquid n-pentane (617b4be5db381.jpg)) is introduced into a 10.0 L vessel containing 12.12 atm of oxygen gas at 300 K and ignited, yielding carbon dioxide and water. If the vessel is then cooled to 263 K, what will be the gas pressure inside the vessel? (A) 1.42 atm (B) 3.09 atm (C) 10.05 atm (D) 12.15 atm (E) none of these
20. Which of these gas molecules have the highest average velocity at 25°C ? (A) N2 (B) He (C) O2 (D) Ar (E) none of these

申論題 (4)

＜ II ＞計算題 
 (1) A sample of commercial concentrated hydrochloric acid is 36.2% HCl by mass and has a density of 1.190 g/mL. Calculate the molarity (M) of HCl. (617b4c0da36d0.jpg = 36.46 g/mol)

(2) Find the solubility of Cr(OH)3 in a buffer of pH 13.0 617b4c2ba65f2.jpg , 617b4c542356d.jpg of 617b4c44c2732.jpg

(3) Aluminum (Al) reacts with sulfur (S) to form solid aluminum sulfide (Al2S3), as the following equation (unbalanced)； 617b4c71cce5d.jpg

What is the percent yield of aluminum sulfide if 18.5 g of aluminum sulfide is collected when 10.0 g of aluminum reacts with 15.0 g of sulfur. 617b4c8b40b63.jpg
(4) At a given temperature, you have a mixture of benzene (vapor pressure of pure benzene = 745 torr) and toluene (vapor pressure of pure toluene = 290 torr). The mole fraction of toluene in the solution is 0.420. Assuming ideal behavior, calculate the mole fraction of benzene in the vapor above the solution.